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The iodine "clock reaction" involves the following sequence of reactions occurring in a reaction mixture in a single beaker. 1) IO3-(aq) + 5I-(aq) + 6H+(aq) 3I2(aq) + 3H2O(l) 2) I2(aq) + 2S2O32-(aq) 2I-(aq) + S4O62-(aq) The molecular iodine (I2) formed in reaction 1 is immediately used up in reaction 2, so that no iodine accumulates. What is the overall reaction occurring in this experiment?


A) IO3-(aq) + 3I-(aq) + 2S2O32-(aq) + 6H+(aq) 2I2(aq) + S4O62-(aq) + 3H2O(l)
B) IO3-(aq) + 4S2O32-(aq) + 6H+(aq) I-(aq) + 2S4O62-(aq) + 3H2O(l)
C) IO3-(aq) + 6S2O32-(aq) + 6H+(aq) I-(aq) + 3S4O62-(aq) + 3H2O(l)
D) IO3-(aq) + I2(aq) + 8S2O32-(aq) + 6H+(aq) 3I-(aq) + 4S4O62-(aq) + 3H2O(l)
E) IO3-(aq) + 2I2(aq) + 6S2O32-(aq) + 6H+(aq) 5I-(aq) + 3S4O62-(aq) + 3H2O(l)

F) B) and D)
G) B) and E)

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Copper(II) sulfate pentahydrate, CuSO4·5H2O, is used as a fungicide and algicide. Calculate the mass of oxygen in 1.000 mol of CuSO4·5H2O.


A) 249.7 g
B) 144.0 g
C) 96.00 g
D) 80.00 g
E) 64.00 g

F) A) and B)
G) None of the above

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How many molecules of molecular oxygen react with four molecules of NH3 to form four molecules of nitrogen monoxide and six molecules of water?


A) 2
B) 10
C) 3
D) 4
E) 5

F) A) and C)
G) A) and E)

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Which of the following samples contains the greatest total number atoms?


A) 50.0 g of Li2O
B) 75.0 g of CaO
C) 200.0 g of Fe2O3
D) 50.0 g of CO2
E) 100.0 g of SO3

F) A) and D)
G) D) and E)

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Household sugar, sucrose, has the molecular formula C12H22O11. What is the % of carbon in sucrose, by mass?


A) 26.7%
B) 33.3%
C) 41.4%
D) 42.1%
E) 52.8%

F) A) and E)
G) A) and B)

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Calculate the number of oxygen atoms in 29.34 g of sodium sulfate, Na2SO4.


A) 1.244 × 1023 O atoms
B) 4.976 × 1023 O atoms
C) 2.409 × 1024 O atoms
D) 2.915 × 1024 O atoms
E) 1.166 × 1025 O atoms

F) A) and C)
G) B) and D)

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A compound consisting of C, H, and O only, has a molar mass of 331.5 g/mol. Combustion of 0.1000 g of this compound caused a 0.2921 g increase in the mass of the CO2 absorber and a 0.0951 g increase in the mass of the H2O absorber. What is the empirical formula of the compound?

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C22H35O2

Sulfur dioxide reacts with chlorine to produce thionyl chloride (used as a drying agent for inorganic halides) and dichlorine oxide (used as a bleach for wood, pulp, and textiles) . SO2(g) + 2Cl2(g) SOCl2(g) + Cl2O(g) If 0.400 mol of Cl2 reacts with excess SO2, how many moles of Cl2O are formed?


A) 0.800 mol
B) 0.400 mol
C) 0.200 mol
D) 0.100 mol
E) 0.0500 mol

F) A) and C)
G) C) and D)

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In a blast furnace, elemental iron is produced from a mixture of coke (C) , iron ore (Fe3O4) , and other reactants. An important reaction sequence is 2C(s) + O2(g) 2CO(g) Fe3O4(s) + 4CO(g) 3Fe(l) + 4CO2(g) How many moles of iron can be formed in this sequence when 1.00 mol of carbon, as coke, is consumed?


A) 6.00 mol Fe
B) 3.00 mol Fe
C) 1.33 mol Fe
D) 1.25 mol Fe
E) 0.750 mol Fe

F) A) and C)
G) A) and D)

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How many protons are there in a molecule of adrenaline (C9H13NO3) , a neurotransmitter and hormone?


A) 22
B) 26
C) 43
D) 98
E) 183

F) C) and E)
G) C) and D)

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D

Balance the following equation: C8H18O3(l) + O2(g) H2O(g) + CO2(g)


A) C8H18O3(l) + 8O2(g) 9H2O(g) + 8CO2(g)
B) C8H18O3(l) + 11O2(g) 9H2O(g) + 8CO2(g)
C) 2C8H18O3(l) + 22O2(g) 9H2O(g) + 16CO2(g)
D) C8H18O3(l) + 13O2(g) 18H2O(g) + 8CO2(g)
E) 2C8H18O3(l) + 17O2(g) 18H2O(g) + 16CO2(g)

F) A) and E)
G) A) and B)

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Potassium chloride is used as a substitute for sodium chloride for individuals with high blood pressure. Identify the limiting reactant and determine the mass of the excess reactant remaining when 7.00 g of chlorine gas reacts with 5.00 g of potassium to form potassium chloride.


A) Potassium is the limiting reactant; 2.47 g of chlorine remain.
B) Potassium is the limiting reactant; 7.23 g of chlorine remain.
C) Chlorine is the limiting reactant; 4.64 g of potassium remain.
D) Chlorine is the limiting reactant; 2.70 g of potassium remain.
E) No limiting reagent: the reactants are present in the correct stoichiometric ratio.

F) A) and B)
G) A) and C)

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Calculate the mass in grams of 8.35 × 1022 molecules of CBr4.


A) 0.0217 g
B) 0.139 g
C) 7.21 g
D) 12.7 g
E) 46.0 g

F) None of the above
G) All of the above

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E

Methanol (CH4O) is converted to bromomethane (CH3Br) as follows: CH4O + HBr CH3Br + H2O If 12.23 g of bromomethane are produced when 5.00 g of methanol is reacted with excess HBr, what is the percentage yield?


A) 40.9%
B) 82.6%
C) 100.%
D) 121%
E) 245%

F) B) and E)
G) B) and C)

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In a correctly balanced equation, the number of reactant molecules must equal the number of product molecules.

A) True
B) False

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Phosphine, an extremely poisonous and highly reactive gas, will react with oxygen to form tetraphosphorus decaoxide and water. PH3(g) + O2(g) P4O10(s) + H2O(g) [unbalanced] Calculate the mass of P4O10(s) formed when 225 g of PH3 reacts with excess oxygen.


A) 1880 g
B) 940. g
C) 900. g
D) 470 g
E) 56.3 g

F) A) and D)
G) None of the above

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Analysis of a carbohydrate showed that it consisted of 40.0 % C, 6.71 % H, and 53.3 % O by mass. Its molecular mass was found to be between 140 and 160 amu. What is the molecular formula of this compound?


A) C4H8O6
B) C5H10O5
C) C5H12O5
D) C6H12O4
E) none of the above

F) C) and D)
G) B) and E)

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Sodium bromate is used in a mixture which dissolves gold from its ores. Calculate the mass in grams of 4.68 mol of sodium bromate.


A) 706 g
B) 482 g
C) 383 g
D) 32.2 g
E) 0.0310 g

F) D) and E)
G) A) and E)

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A single atom of hydrogen has a mass of 1.0 amu, while a mole of hydrogen atoms has a mass of 1.0 g. Select the correct conversion factor between atomic mass units and grams.


A) 1 amu = 1 g exactly
B) 1 amu = 6.0 × 1023 g
C) 1 g = 6.0 × 1023 amu
D) 1 g = 1.7 × 10-24 amu
E) none of the above

F) B) and D)
G) None of the above

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Calculate the molar mass of (NH4) 3AsO4.


A) 417.80 g/mol
B) 193.03 g/mol
C) 165.02 g/mol
D) 156.96 g/mol
E) 108.96 g/mol

F) D) and E)
G) None of the above

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