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Why do molecules become IR-active?


A) Because they are in constant motion.
B) Because they can absorb IR radiation (a photon of a specific wavelength in the IR region) because their dipole moments constantly change as the bond lengths change.
C) Because they vibrate at low temperatures.
D) Because their net dipole is zero.
E) Because they are very close together.

F) None of the above
G) A) and D)

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________ is the major mechanism by which molecular oxygen is regenerated from carbon dioxide and water.

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Which of the following is emitted into the atmosphere when a volcano erupts?


A) H2S
B) N2
C) HCl
D) sulfuric acid aerosol
E) All of the answers are correct.

F) A) and E)
G) A) and D)

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How many different ways can water vibrate?

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Due to a highway accident, 150 L of concentrated hydrochloric acid (12.0 M) is released into a lake containing 5.0 × 105 m3 of water. If the pH of this lake was 7.0 prior to the accident, what is the pH of the lake following the accident?


A) 5.44
B) 8.56
C) 8.44
D) 5.56
E) 2.44

F) C) and E)
G) A) and E)

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What is the name given to the spectacular celestial light shown in the sky resulting from electrons and protons in space ejected from solar eruptions?


A) auroras
B) astral lights
C) stellar explosions
D) cosmic flares
E) solar flare

F) D) and E)
G) B) and D)

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Which one of the following would slow the rate of increase of atmospheric CO2?


A) building and operating more coal-fired power plants
B) more use of catalytic converters in cars to produce complete combustion
C) use of hydrogen fuel produced using solar or nuclear energy
D) conversion of nuclear power plants to methane-burning power plants
E) clearing and burning the tropical rain forests

F) B) and D)
G) C) and D)

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Heat is radiated from Earth to space predominately in the form of


A) infrared radiation.
B) radioactivity.
C) visible light.
D) solar flares.
E) UV radiation.

F) A) and B)
G) A) and C)

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The bond energy of N2 is 160 kJ/mol. What is the wavelength of a photon that can cause the dissociation of a N2 molecule? (h = 6.63 × 10-34J s; c = 3.0 × 108m/s and Avogadro's number = 6.022 × 1023 molecules/mole)


A) 749 nm
B) 366 nm
C) 233 nm
D) 375 nm
E) 650 nm

F) C) and D)
G) None of the above

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What is defined as the conversion of molecular nitrogen into nitrogen compounds?


A) nitrogen fixation
B) nitrogen conversion
C) nitrogenation
D) nitrogen turnover
E) nitrogen cycle

F) D) and E)
G) A) and E)

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What element is the most abundant by mass in Earth's crust?


A) Fe
B) H
C) K
D) P
E) O

F) A) and B)
G) B) and D)

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Which of the following oxides would not react with water to form an acidic solution?


A) SO3
B) CO2
C) BaO
D) NO2

E) A) and B)
F) None of the above

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The Earth's core consists mainly of


A) Ni.
B) O.
C) Al.
D) Si.
E) Fe.

F) D) and E)
G) B) and E)

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How many different ways can a CO2 molecule vibrate?


A) 1
B) 2
C) 3
D) 4
E) millions

F) D) and E)
G) A) and E)

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Plants extract phosphate from the soil


A) by converting it to the dihydrogen phosphate ion by addition of acid to the soil near roots.
B) by converting it to phosphoric acid.
C) by osmosis.
D) by leaching.
E) by fixation.

F) A) and B)
G) B) and E)

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Which of the following does not readily interact with ozone?


A) Chlorine
B) Nitrogen oxides
C) Chlorine nitrate
D) Carbon fluorides

E) All of the above
F) A) and C)

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Volcanoes


A) produce about two-thirds of the sulfur in the air.
B) are involved in the production of sulfuric acid "aerosols", which persist above the troposphere.
C) produce localized areas of lower temperature.
D) All of the choices are correct.
E) None of these choices.

F) B) and C)
G) D) and E)

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The principal contributor to acid rain is


A) CO2.
B) SO2.
C) O3.
D) NO2.

E) A) and D)
F) C) and D)

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The average person breathes about 20 m3 of air a day. What weight of particulates would a person breathe in a day if the particulate level were 400 micrograms per cubic meter?

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The process in which a gaseous substance is converted into a condensed, more usable chemical substance is called


A) differentiation.
B) liquefaction.
C) fixation.
D) deposition.
E) remediation.

F) A) and D)
G) A) and C)

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