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The maximum number of phases of a single substance which can coexist in equilibrium is two.

A) True
B) False

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The Clausius-Clapeyron equation is used in calculations of


A) melting and freezing points.
B) vapor pressures of liquids.
C) osmotic pressures of solutions.
D) heats of vaporization at different temperatures.
E) crystal structure.

F) A) and E)
G) C) and D)

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When the adhesive forces between a liquid and the walls of a capillary tube are greater than the cohesive forces within the liquid


A) the liquid level in a capillary tube will rise above the surrounding liquid and the surface in the capillary tube will have a convex meniscus.
B) the liquid level in a capillary tube will rise above the surrounding liquid and the surface in the capillary tube will have a concave meniscus.
C) the liquid level in a capillary tube will drop below the surrounding liquid and the surface in the capillary tube will have a convex meniscus.
D) the liquid level in a capillary tube will drop below the surrounding liquid and the surface in the capillary tube will have a concave meniscus.
E) None of these choices is correct.

F) None of the above
G) All of the above

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Iron crystallizes in the body-centered cubic lattice. What is the coordination number for Fe?


A) 4
B) 6
C) 8
D) 10
E) 12

F) D) and E)
G) C) and D)

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The coordination number of sodium and chloride ions in the NaCl lattice, are, respectively:


A) 10 and 10
B) 8 and 8
C) 6 and 6
D) 4 and 4
E) None of these choices is correct.

F) B) and C)
G) B) and E)

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Select the pair of substances in which the one with the higher vapor pressure at a given temperature is listed first.


A) C7H16, C5H12
B) CCl4, CBr4
C) H2O, H2S
D)
CH3CH2OH, CH3
Select the pair of substances in which the one with the higher vapor pressure at a given temperature is listed first. A)  C<sub>7</sub>H<sub>16</sub>, C<sub>5</sub>H<sub>12</sub> B)  CCl<sub>4</sub>, CBr<sub>4</sub> C)  H<sub>2</sub>O, H<sub>2</sub>S D)   CH<sub>3</sub>CH<sub>2</sub>OH, CH<sub>3</sub> <sub> </sub>   O   CH<sub>3</sub> E)  Xe, Kr O
Select the pair of substances in which the one with the higher vapor pressure at a given temperature is listed first. A)  C<sub>7</sub>H<sub>16</sub>, C<sub>5</sub>H<sub>12</sub> B)  CCl<sub>4</sub>, CBr<sub>4</sub> C)  H<sub>2</sub>O, H<sub>2</sub>S D)   CH<sub>3</sub>CH<sub>2</sub>OH, CH<sub>3</sub> <sub> </sub>   O   CH<sub>3</sub> E)  Xe, Kr CH3
E) Xe, Kr

F) A) and B)
G) C) and E)

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Draw a fully labeled phase diagram (P versus T) of a substance whose solid phase can melt due to applied pressure (i.e., solid is less dense than liquid). Clearly label the triple point and the critical temperature on your diagram.

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The energy gap between the conduction band and the valence band is large for


A) conductors.
B) semiconductors.
C) superconductors.
D) insulators.
E) alloys.

F) A) and B)
G) C) and E)

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Octane is a component of fuel used in internal combustion engines. The dominant intermolecular forces in octane are


A) dipole-dipole forces.
B) London dispersion forces.
C) hydrogen bonding.
D) covalent bonds.
E) carbon-hydrogen bonds.

F) B) and C)
G) A) and B)

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The strongest intermolecular interactions between hydrogen fluoride (HF) molecules arise from


A) dipole-dipole forces.
B) London dispersion forces.
C) hydrogen bonding.
D) ion-dipole interactions.
E) ionic bonds.

F) A) and E)
G) None of the above

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In metals, the conduction bands and valence bands of the molecular orbitals are separated by a large energy gap.

A) True
B) False

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Which of the following terms refers to the resistance of a liquid to flow?


A) surface tension
B) capillary action
C) viscosity
D) adhesion
E) cohesion

F) C) and E)
G) A) and E)

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The highest temperature at which superconductivity has been achieved is approximately:


A) 4 K
B) 30 K
C) 70 K
D) 100 K
E) 130 K

F) B) and E)
G) C) and D)

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List the three common classes of liquid crystals in order of decreasing degree of order.

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smectic > ...

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Which of the following liquid substances would you expect to have the lowest surface tension?


A) Pb
B) CH3OCH3
C) HOCH2CH2OH
D) H2O
E) CH3CH2OH

F) A) and D)
G) A) and E)

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Which of the following should have the lowest boiling point?


A) C5H12
B) C6H14
C) C8H18
D) C10H22
E) C12H26

F) C) and D)
G) B) and E)

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When the electron cloud of a molecule is easily distorted, the molecule has a high _____________.


A) polarity
B) polarizability
C) dipole moment
D) van der Waals radius
E) compressibility

F) A) and C)
G) A) and E)

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Which one of the following substances does not exist in the indicated solid type?


A) graphite - network
B) Na - metallic
C) SiO2 - molecular
D) NaCl - ionic
E) diamond - network

F) C) and D)
G) B) and C)

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In an ionic solid MX consisting of the monatomic ions, M+ and X-, the coordination number of M+ is ___.


A) 1
B) 2
C) 6
D) 8
E) impossible to predict without knowing the crystal structure of MX

F) C) and E)
G) None of the above

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What adjective best describes the solid compound IF7?


A) metallic
B) amorphous
C) covalent network
D) molecular
E) ionic

F) A) and B)
G) All of the above

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